Synthesis and Applications of Polymeric Reagent p-Substituted Triphenylamine

Chemical modification of chloromethylstyrene - styrene copolymer throughout reaction p-substituted carboxylic acid group bis-(4,4`-dibromo)-4``-triphenylamine with the chloromethyl attached to a phenyl was carried out on soluble and polymeric cross-linked copolymer. oxidation neutral triphenylamine antimony pentachloride in dichloromethane solvent gives corresponding cation radical salt counter ion hexachloride (SbCl6-). The isolated deep blue color is or insoluble (resin) form used as thermal cationic initiator for polymerization epoxy vinyl monomers at room temperature. resin showed good activity stability compared radical, both can initiate cyclohexene oxide N-vinylcarbazole